Rid Enum is a RID cycling attack that attempts to enumerate user accounts through null sessions and the SID to RID enum. If you specify a password file, it will automatically attempt to brute force the user accounts when its finished enumerating.
Skipfish is an active web application security reconnaissance tool. It prepares an interactive sitemap for the targeted site by carrying out a recursive crawl and dictionary-based probes. The resulting map is then annotated with the output from a number of active (but hopefully non-disruptive) security checks.
smtp-user-enum is a tool for enumerating OS-level user accounts on Solaris via the SMTP service (sendmail). Enumeration is performed by inspecting the responses to VRFY, EXPN and RCPT TO commands. It could be adapted to work against other vulnerable SMTP daemons, but this hasn’t been done as of v1.0.